ICSC 1389 - TRIMETHYL BENZENE (MIXED ISOMERS)

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TRIMETHYL BENZENE (MIXED ISOMERS)	ICSC: 1389 (June 2002)
Benzene, trimethyl (isomers) Methylxylene

CAS #: 25551-13-7

UN #: 1993

EC Number: 247-099-9

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Flammable. Above 44°C explosive vapour/air mixtures may be formed.	NO open flames, NO sparks and NO smoking. Above 44°C use a closed system, ventilation and explosion-proof electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).	Use alcohol-resistant foam, dry powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

PREVENT GENERATION OF MISTS!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Confusion. Cough. Dizziness. Drowsiness. Headache. Sore throat. Vomiting.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Redness. Dry skin.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Wear safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	See Inhalation.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 3; UN Pack Group: III
STORAGE
Fireproof. Separated from strong oxidants. Well closed. Keep in a well-ventilated room.
PACKAGING
See Notes.

TRIMETHYL BENZENE (MIXED ISOMERS)

ICSC: 1389

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers Chemical dangers Decomposes on burning. This produces toxic and irritating fumes. Reacts violently with strong oxidants. This generates fire and explosion hazard.	Formula: C₉H₁₂ Molecular mass: 120.2 Boiling point: 165-176°C Melting point: -25 - -45°C Relative density (water = 1): 0.86-0.89 Solubility in water: very poor Vapour pressure, kPa at 20°C: 0.18 - 0.25 Relative vapour density (air = 1): 4.1 Flash point: 44-53°C c.c. Auto-ignition temperature: 470-550°C Octanol/water partition coefficient as log Pow: 3.4/3.8

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers

Chemical dangers
Decomposes on burning. This produces toxic and irritating fumes. Reacts violently with strong oxidants. This generates fire and explosion hazard.

Formula: C₉H₁₂
Molecular mass: 120.2
Boiling point: 165-176°C
Melting point: -25 - -45°C
Relative density (water = 1): 0.86-0.89
Solubility in water: very poor
Vapour pressure, kPa at 20°C: 0.18 - 0.25
Relative vapour density (air = 1): 4.1
Flash point: 44-53°C c.c.
Auto-ignition temperature: 470-550°C
Octanol/water partition coefficient as log Pow: 3.4/3.8

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation. Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system.	Inhalation risk A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster. Effects of long-term or repeated exposure The substance defats the skin, which may cause dryness or cracking. Repeated or prolonged inhalation may cause effects on the lungs. This may result in chronic bronchitis. The substance may have effects on the blood and central nervous system. See Notes.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system.

Inhalation risk
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.

Effects of long-term or repeated exposure
The substance defats the skin, which may cause dryness or cracking. Repeated or prolonged inhalation may cause effects on the lungs. This may result in chronic bronchitis. The substance may have effects on the blood and central nervous system. See Notes.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 25 ppm as TWA. MAK: 100 mg/m³, 20 ppm; peak limitation category: II(2); pregnancy risk group: C

ENVIRONMENT
The substance is harmful to aquatic organisms. Bioaccumulation of this chemical may occur in fish.

NOTES
Use of alcoholic beverages enhances the harmful effect. Depending on the degree of exposure, periodic medical examination is suggested. See ICSCs 1155, 1362 and 1433.

ADDITIONAL INFORMATION

EC Classification

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