ICSC 1212 - LEAD(II) ARSENITE

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LEAD(II) ARSENITE	ICSC: 1212 (June 2011)
Lead arsenite Lead metaarsenite Arsenious acid lead salt

CAS #: 10031-13-7

UN #: 1618

EC Number: 233-083-9

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.		In case of fire in the surroundings, use appropriate extinguishing media.

PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat.	Use closed system, ventilation or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin		Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Seek medical attention if you feel unwell.
Eyes	Redness. Pain.	Wear face shield or eye protection in combination with breathing protection if powder.	Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer for medical attention.
Ingestion	Abdominal pain. Burning sensation in the throat and chest. Vomiting. Headache. Diarrhoea. Weakness. Shock or collapse.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer immediately for medical attention.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Vacuum with specialist equipment (See Notes) or carefully sweep into containers. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Toxic if swallowed Causes eye irritation May cause cancer Suspected of damaging fertility or the unborn child Causes damage to digestive tract if swallowed Causes damage to organs through prolonged or repeated exposure Harmful to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: II
STORAGE
Separated from strong oxidants, strong acids and food and feedstuffs. Well closed. Store in an area without drain or sewer access.
PACKAGING
Do not transport with food and feedstuffs. Marine pollutant.

LEAD(II) ARSENITE

ICSC: 1212

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance WHITE POWDER. Physical dangers No data. Chemical dangers Decomposes on heating. This produces toxic fumes of arsenic and lead. Reacts with oxidants. Reacts with strong acids. This produces toxic gas (arsine - see ICSC 0222).	Formula: As₂O₄Pb / Pb(AsO₂)₂ Molecular mass: 421.0 Density: 5.85 g/cm³ Solubility in water: none

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
WHITE POWDER.

Physical dangers
No data.

Chemical dangers
Decomposes on heating. This produces toxic fumes of arsenic and lead. Reacts with oxidants. Reacts with strong acids. This produces toxic gas (arsine - see ICSC 0222).

Formula: As₂O₄Pb / Pb(AsO₂)₂
Molecular mass: 421.0
Density: 5.85 g/cm³
Solubility in water: none

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation and by ingestion. Effects of short-term exposure The substance is irritating to the eyes and respiratory tract. Ingestion could cause effects on the gastrointestinal tract. This may result in severe gastroenteritis, loss of fluids and electrolytes, cardiac disorders and shock. Exposure far above the OEL could cause death. The effects may be delayed. Medical observation is indicated.	Inhalation risk A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered. Effects of long-term or repeated exposure The substance may have effects on the skin, mucous membranes, bone marrow, blood, central nervous system, peripheral nervous system and liver. This may result in pigmentation disorders, perforation of the nasal septum, anaemia, nervous system impairment and liver impairment. This substance is carcinogenic to humans. Causes toxicity to human reproduction or development.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes and respiratory tract. Ingestion could cause effects on the gastrointestinal tract. This may result in severe gastroenteritis, loss of fluids and electrolytes, cardiac disorders and shock. Exposure far above the OEL could cause death. The effects may be delayed. Medical observation is indicated.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

Effects of long-term or repeated exposure
The substance may have effects on the skin, mucous membranes, bone marrow, blood, central nervous system, peripheral nervous system and liver. This may result in pigmentation disorders, perforation of the nasal septum, anaemia, nervous system impairment and liver impairment. This substance is carcinogenic to humans. Causes toxicity to human reproduction or development.

OCCUPATIONAL EXPOSURE LIMITS
EU-OEL: (inhalable fraction): 0.01 mg/m³ as TWA; (see Notes)

ENVIRONMENT
The substance is harmful to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.

NOTES
NEVER use a domestic-type vacuum cleaner to vacuum the substance, only use specialist equipment. Depending on the degree of exposure, periodic medical examination is suggested. Do NOT take working clothes home. For the copper smelting sector, the EU OEL value shall apply from 11 July 2023.

ADDITIONAL INFORMATION

EC Classification
Symbol: T, N; R: 23/25-50/53; S: (1/2)-20/21-28-45-60-61; Note:

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