ICSC 0691 - 1,3-DINITROBENZENE

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1,3-DINITROBENZENE	ICSC: 0691 (May 2002)
1,3-Dinitrobenzol m-Dinitrobenzene 1,3-DNB

CAS #: 99-65-0

UN #: 3443

EC Number: 202-776-8

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air.	NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.	Use water spray, foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.

PREVENT DISPERSION OF DUST! STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Burning sensation. Blue lips, fingernails and skin. Dizziness. Headache. Nausea. Weakness. Laboured breathing.	Use local exhaust or breathing protection.	Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Skin	MAY BE ABSORBED! See Inhalation.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .
Eyes	Redness. Pain.	Wear face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	See Inhalation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Consult an expert! Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: complete protective clothing including self-contained breathing apparatus.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: II
STORAGE
Separated from strong oxidants, strong bases and food and feedstuffs. See Chemical Dangers.
PACKAGING
Do not transport with food and feedstuffs.

1,3-DINITROBENZENE

ICSC: 0691

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance YELLOW CRYSTALS. Physical dangers Dust explosion possible if in powder or granular form, mixed with air. Chemical dangers May explode on heating even in the absence of air. On combustion, forms toxic gases and fumes including nitrogen oxides. Reacts violently with strong oxidants, strong bases and reducing metals (tin and zinc). This generates fire and explosion hazard. Attacks some plastics and rubber.	Formula: C₆H₄N₂O₄ / C₆H₄(NO₂)₂ Molecular mass: 168.1 Boiling point: 300-303°C Melting point: 90°C Density: 1.6 g/cm³ Solubility in water: very poor Vapour pressure, kPa at 20°C: <0.1 Relative vapour density (air = 1): 5.8 Flash point: 149°C Octanol/water partition coefficient as log Pow: 1.49

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
YELLOW CRYSTALS.

Physical dangers
Dust explosion possible if in powder or granular form, mixed with air.

Chemical dangers
May explode on heating even in the absence of air. On combustion, forms toxic gases and fumes including nitrogen oxides. Reacts violently with strong oxidants, strong bases and reducing metals (tin and zinc). This generates fire and explosion hazard. Attacks some plastics and rubber.

Formula: C₆H₄N₂O₄ / C₆H₄(NO₂)₂
Molecular mass: 168.1
Boiling point: 300-303°C
Melting point: 90°C
Density: 1.6 g/cm³
Solubility in water: very poor
Vapour pressure, kPa at 20°C: <0.1
Relative vapour density (air = 1): 5.8
Flash point: 149°C
Octanol/water partition coefficient as log Pow: 1.49

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Effects of short-term exposure The substance is irritating to the eyes and respiratory tract. The substance may cause effects on the blood. This may result in the formation of methaemoglobin. The effects may be delayed. Medical observation is indicated.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure The substance may have effects on the blood. This may result in anaemia. The substance may have effects on the liver. This may result in liver impairment. The substance may have effects on the nervous system. Animal tests show that this substance possibly causes toxicity to human reproduction or development. May cause impaired vision.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes and respiratory tract. The substance may cause effects on the blood. This may result in the formation of methaemoglobin. The effects may be delayed. Medical observation is indicated.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure
The substance may have effects on the blood. This may result in anaemia. The substance may have effects on the liver. This may result in liver impairment. The substance may have effects on the nervous system. Animal tests show that this substance possibly causes toxicity to human reproduction or development. May cause impaired vision.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 0.15 ppm as TWA; (skin); BEI issued. MAK: skin absorption (H); carcinogen category: 3

ENVIRONMENT
The substance is toxic to aquatic organisms.

NOTES
Use of alcoholic beverages enhances the harmful effect. Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. See ICSCs 0460, 0692 and 0725.

ADDITIONAL INFORMATION

EC Classification
Symbol: T+, N; R: 26/27/28-33-50/53; S: (1/2)-28-36/37-45-60-61; Note: C

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