ICSC 0314 - ETHYL CARBAMATE

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ETHYL CARBAMATE	ICSC: 0314 (May 2010)
Carbamic acid ethyl ester Ethyl urethane Urethane

CAS #: 51-79-6

EC Number: 200-123-1

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Use powder, alcohol-resistant foam, water spray, carbon dioxide.

AVOID ALL CONTACT!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation		Use local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin		Protective gloves.	Rinse skin with plenty of water or shower.
Eyes		Wear face shield or eye protection in combination with breathing protection if powder.	Rinse with plenty of water (remove contact lenses if easily possible).
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: chemical protection suit including self-contained breathing apparatus. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER May be harmful if swallowed May cause cancer May cause harm to breast-fed children May cause damage to the nervous system Transportation UN Classification
STORAGE
See Chemical Dangers. Well closed.
PACKAGING

ETHYL CARBAMATE

ICSC: 0314

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance ODOURLESS COLOURLESS CRYSTALS. PELLETS OR WHITE GRANULAR POWDER. Physical dangers No data. Chemical dangers Decomposes on heating. This produces toxic fumes including nitrogen oxides. Reacts with strong oxidants, strong acids and strong bases.	Formula: C₃H₇NO₂ / NH₂COOC₂H₅ Molecular mass: 89.09 Boiling point: 185°C Melting point: 49°C Relative density (water = 1): 0.98 Solubility in water, g/100ml: 200 Vapour pressure, Pa at 20°C: 5 Relative vapour density (air = 1): 3.1 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00 Flash point: 92°C c.c. Octanol/water partition coefficient as log Pow: -0.15

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
ODOURLESS COLOURLESS CRYSTALS. PELLETS OR WHITE GRANULAR POWDER.

Physical dangers
No data.

Chemical dangers
Decomposes on heating. This produces toxic fumes including nitrogen oxides. Reacts with strong oxidants, strong acids and strong bases.

Formula: C₃H₇NO₂ / NH₂COOC₂H₅
Molecular mass: 89.09
Boiling point: 185°C
Melting point: 49°C
Relative density (water = 1): 0.98
Solubility in water, g/100ml: 200
Vapour pressure, Pa at 20°C: 5
Relative vapour density (air = 1): 3.1
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 92°C c.c.
Octanol/water partition coefficient as log Pow: -0.15

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by ingestion. Effects of short-term exposure The substance may cause effects on the nervous system. Exposure could cause lowering of consciousness.	Inhalation risk Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly. Effects of long-term or repeated exposure This substance is probably carcinogenic to humans.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by ingestion.

Effects of short-term exposure
The substance may cause effects on the nervous system. Exposure could cause lowering of consciousness.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

Effects of long-term or repeated exposure
This substance is probably carcinogenic to humans.

OCCUPATIONAL EXPOSURE LIMITS
MAK: skin absorption (H); carcinogen category: 2; germ cell mutagen group: 5

ENVIRONMENT

NOTES
Do NOT take working clothes home.

ADDITIONAL INFORMATION

EC Classification
Symbol: T; R: 45; S: 53-45

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