ICSC 0219 - sec-AMYL ACETATE

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sec-AMYL ACETATE	ICSC: 0219 (November 2000)
2-Pentyl acetate Acetic acid, 2-pentyl ester 1-Methylbutyl acetate

CAS #: 626-38-0

UN #: 1104

EC Number: 210-946-8

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Flammable. Above 32°C explosive vapour/air mixtures may be formed.	NO open flames, NO sparks and NO smoking. Above 32°C use a closed system, ventilation and explosion-proof electrical equipment.	Use alcohol-resistant foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Dizziness. Drowsiness. Headache. Sore throat.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest.
Skin	Dry skin. Redness.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Wear face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth. Give one or two glasses of water to drink.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 3; UN Pack Group: III
STORAGE
Fireproof. Separated from strong oxidants.
PACKAGING

sec-AMYL ACETATE

ICSC: 0219

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers The vapour is heavier than air. Chemical dangers Reacts with oxidants. This generates fire and explosion hazard. Attacks many plastics.	Formula: C₇H₁₄O₂ / CH₃COOCH(CH₃)C₃H₇ Molecular mass: 130.2 Boiling point: 121°C Melting point: -148°C Relative density (water = 1): 0.86 Solubility in water: poor Vapour pressure, kPa at 20°C: 0.93 Relative vapour density (air = 1): 4.5 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.03 Flash point: 32°C c.c. Auto-ignition temperature: 380°C Explosive limits, vol% in air: 1.0-7.5 Octanol/water partition coefficient as log Pow: 2.26

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air.

Chemical dangers
Reacts with oxidants. This generates fire and explosion hazard. Attacks many plastics.

Formula: C₇H₁₄O₂ / CH₃COOCH(CH₃)C₃H₇
Molecular mass: 130.2
Boiling point: 121°C
Melting point: -148°C
Relative density (water = 1): 0.86
Solubility in water: poor
Vapour pressure, kPa at 20°C: 0.93
Relative vapour density (air = 1): 4.5
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.03
Flash point: 32°C c.c.
Auto-ignition temperature: 380°C
Explosive limits, vol% in air: 1.0-7.5
Octanol/water partition coefficient as log Pow: 2.26

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour. Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract. Exposure at high levels could cause lowering of consciousness.	Inhalation risk A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure The substance defats the skin, which may cause dryness or cracking.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. Exposure at high levels could cause lowering of consciousness.

Inhalation risk
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
The substance defats the skin, which may cause dryness or cracking.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 50 ppm as TWA; 100 ppm as STEL. MAK: 270 mg/m³, 50 ppm; peak limitation category: I(1); pregnancy risk group: D. EU-OEL: 270 mg/m³, 50 ppm as TWA; 540 mg/m³, 100 ppm as STEL

ENVIRONMENT

NOTES
Use of alcoholic beverages enhances the harmful effect.

ADDITIONAL INFORMATION

EC Classification
R: 10-66; S: (2)-23-25; Note: C

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