ICSC 0081 - TRICHLOROETHYLENE

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TRICHLOROETHYLENE	ICSC: 0081 (April 2013)
1,1,2-Trichloroethylene Trichloroethene Ethylene trichloride Acetylene trichloride Tri Chlorylen TCE Trilene Trichlor

CAS #: 79-01-6

UN #: 1710

EC Number: 201-167-4

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible under specific conditions. See Notes. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames, NO sparks and NO smoking. NO contact with hot surfaces, strong bases or finely divided metals. Prevent build-up of electrostatic charges (e.g., by grounding).	In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water.

PREVENT GENERATION OF MISTS! AVOID ALL CONTACT!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Dizziness. Drowsiness. Headache. Weakness. Nausea. Unconsciousness.	Use closed system.	Fresh air, rest. Artificial respiration may be needed. Refer immediately for medical attention.
Skin	Dry skin. Redness.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness. Pain.	Wear safety spectacles or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Sore throat. Aspiration hazard! See Inhalation. Cardiac dysrhythmia. Respiratory arrest.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance and complete protective clothing. Ventilation. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria May be harmful if swallowed Causes skin irritation Causes serious eye irritation Suspected of causing genetic defects May cause cancer May cause drowsiness or dizziness May be harmful if swallowed and enters airways Harmful to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: III
STORAGE
Separated from metals, strong bases, food and feedstuffs, combustible substances and ignition sources. See Chemical Dangers. Dry. Keep in the dark. Keep in a well-ventilated room. Cool.
PACKAGING
Do not transport with food and feedstuffs. Marine pollutant.

TRICHLOROETHYLENE

ICSC: 0081

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers The vapour is heavier than air. As a result of flow, agitation, etc., electrostatic charges can be generated. Chemical dangers Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes of phosgene and hydrogen chloride. Decomposes on contact with strong alkali. This produces dichloroacetylene. This increases fire hazard. Reacts violently with finely divided metals. This generates fire and explosion hazard. Slowly decomposed by light in the presence of moisture. This produces corrosive hydrochloric acid.	Formula: C₂HCl₃ / ClCH=CCl₂ Molecular mass: 131.4 Boiling point: 87°C Melting point: -86°C Relative density (water = 1): 1.5 (20°C) Solubility in water, g/100ml at 20°C: 0.1 Vapour pressure, kPa at 20°C: 7.8 Relative vapour density (air = 1): 4.5 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.3 Auto-ignition temperature: 410°C Explosive limits, vol% in air: 7.9 - 100 Octanol/water partition coefficient as log Pow: 2.42 Electrical conductivity: 800 pS/m

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air. As a result of flow, agitation, etc., electrostatic charges can be generated.

Chemical dangers
Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes of phosgene and hydrogen chloride. Decomposes on contact with strong alkali. This produces dichloroacetylene. This increases fire hazard. Reacts violently with finely divided metals. This generates fire and explosion hazard. Slowly decomposed by light in the presence of moisture. This produces corrosive hydrochloric acid.

Formula: C₂HCl₃ / ClCH=CCl₂
Molecular mass: 131.4
Boiling point: 87°C
Melting point: -86°C
Relative density (water = 1): 1.5 (20°C)
Solubility in water, g/100ml at 20°C: 0.1
Vapour pressure, kPa at 20°C: 7.8
Relative vapour density (air = 1): 4.5
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.3
Auto-ignition temperature: 410°C
Explosive limits, vol% in air: 7.9 - 100
Octanol/water partition coefficient as log Pow: 2.42
Electrical conductivity: 800 pS/m

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation, by ingestion and through the skin. Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract. If swallowed the substance may cause vomiting and could result in aspiration pneumonitis. The substance may cause effects on the central nervous system, liver and kidneys. This may result in impaired functions. Exposure at high concentrations could cause unconsciousness.	Inhalation risk A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the central nervous system. This may result in fatigue, irritability and mental and memory disturbances. The substance may have effects on the liver, kidneys and immune system. This substance is carcinogenic to humans. Causes toxicity to human reproduction or development.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation, by ingestion and through the skin.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. If swallowed the substance may cause vomiting and could result in aspiration pneumonitis. The substance may cause effects on the central nervous system, liver and kidneys. This may result in impaired functions. Exposure at high concentrations could cause unconsciousness.

Inhalation risk
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the central nervous system. This may result in fatigue, irritability and mental and memory disturbances. The substance may have effects on the liver, kidneys and immune system. This substance is carcinogenic to humans. Causes toxicity to human reproduction or development.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 10 ppm as TWA; 25 ppm as STEL; A2 (suspected human carcinogen); BEI issued. MAK: skin absorption (H); carcinogen category: 1; germ cell mutagen group: 3B. EU-OEL: 54.7 mg/m³, 10 ppm as TWA; 164.1 mg/m³, 30 ppm as STEL; (skin)

ENVIRONMENT
The substance is harmful to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment.

NOTES
Combustible vapour/air mixtures difficult to ignite, may be developed under certain conditions. Use of alcoholic beverages enhances the harmful effect. Depending on the degree of exposure, periodic medical examination is suggested. The odour warning when the exposure limit value is exceeded is insufficient. Do NOT use in the vicinity of a fire or a hot surface, or during welding.

ADDITIONAL INFORMATION

EC Classification
Symbol: T; R: 45-36/38-52/53-67; S: 53-45-61

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