TOLUENE | ICSC: 0078 (November 2023) |
Methylbenzene Toluol Phenylmethane |
CAS #: 108-88-3 |
UN #: 1294 |
EC Number: 203-625-9 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Highly flammable. Vapour/air mixtures are explosive. Risk of fire and explosion on contact with strong oxidants. | NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. NO contact with strong oxidizing agents. | Use foam, powder, carbon dioxide, water spray. In case of fire: keep drums, etc., cool by spraying with water. |
AVOID ALL CONTACT! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Sore throat. Cough. Dizziness. Drowsiness. Headache. Nausea. Unconsciousness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer immediately for medical attention. |
Skin | Redness. Dry skin. | Protective gloves. | First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Rinse and then wash skin with water and soap. Refer for medical attention . |
Eyes | Redness. Pain. | Wear safety goggles. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Aspiration hazard! Burning sensation. Abdominal pain. Vomiting. Further see Inhalation. | Do not eat, drink, or smoke during work. | Rinse mouth. Give nothing to drink. Do NOT induce vomiting. Refer immediately for medical attention. See Notes. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Evacuate danger area! Consult an expert! Personal protection: chemical protection suit and self-contained breathing apparatus. Ventilation. Remove all ignition sources. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Highly flammable liquid and vapourMay be fatal if swallowed and enters airways Causes skin irritation May cause drowsiness or dizziness Suspected of damaging fertility or the unborn child May cause damage to nervous system through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Transportation |
STORAGE | |
Well closed. Fireproof. Separated from strong oxidants. Store in an area without drain or sewer access. Store only in original container. | |
PACKAGING | |
TOLUENE | ICSC: 0078 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C6H5CH3 / C7H8 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 20 ppm as TWA; (OTO); A4 (not classifiable as a human carcinogen); BEI issued. EU-OEL: 192 mg/m3, 50 ppm as TWA; 384 mg/m3, 100 ppm as STEL; (skin) |
ENVIRONMENT |
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The substance is toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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Depending on the degree of exposure, periodic medical examination is suggested. Use of alcoholic beverages enhances the harmful effect. Ingestion of this substance, regardless of the amount ingested, can cause aspiration and thus risk of chemical pneumonitis. The symptoms of chemical pneumonitis do not become manifest until a few hours or even a few days have passed. |
ADDITIONAL INFORMATION | ||
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EC Classification |
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